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Metal-organic framework-derived hollow CoS nanobox for high performance electrochemical energy storage.
- Source :
-
Chemical Engineering Journal . Jun2018, Vol. 341, p618-627. 10p. - Publication Year :
- 2018
-
Abstract
- Graphical abstract Highlights • The ZIF-67-derived hollow CoS shows a high specific capacitance of 720 F g−1. • The anode and cathode of the capacitor are derived from the same precursor. • The surface capacitive contribution is dominated in hollow CoS energy storage. • Assembled capacitor shows a maximum energy density of 80 Wh kg−1. Abstract In this work, hollow CoS nanobox (noted as HCSN) have been successfully synthesized via annealing and hydrothermal process from zeolitic imidazolate framework (ZIF-67) template. When tested as positive electrode materials in alkaline aqueous electrolyte, it shows high specific capacitance of 720 F g−1 at a current density of 1 A g−1, good rate capability (82.1%) and good cycling stability with 86.4% capacitance retention over 10,000 cycles at 10 A g−1. To further demonstrate the advantages of our ZIF-67 derived materials, asymmetric energy storage device was assembled (HCSN//NC), where the as-prepared HCSN was employed as the anode and ZIF-67-derived nanoporous carbon (noted as NC) as the cathode. This device achieves high energy density (80 Wh kg−1 at a specific power density of 882 W kg−1), good rate capability (53.3 Wh kg−1 even at a specific power density of 7.9 kW kg−1) and long-term stability up to 10,000 cycles. More importantly, it could simultaneously light up 12 LEDs in parallel, demonstrating its potential in practical applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13858947
- Volume :
- 341
- Database :
- Academic Search Index
- Journal :
- Chemical Engineering Journal
- Publication Type :
- Academic Journal
- Accession number :
- 131805913
- Full Text :
- https://doi.org/10.1016/j.cej.2018.02.032