Pharmaceuticals and personal care products in the urban river across the megacity Shanghai: Occurrence, source apportionment and a snapshot of influence of rainfall.

Highlights • PPCPs in a typical urban river of megacity Shanghai were investigated. • Untreated wastewater was proposed as a major source of PPCPs in Huangpu River. • Higher concentrations of PPCPs were detected in the lower reach and dry seasons. • Overflow of untreated wastewater led to higher PPCPs load after rainfall. Abstract Occurrence of eleven pharmaceuticals and personal care products (PPCPs) along Huangpu River, a representative urban river of megacity Shanghai, was investigated in four sampling campaigns. The overall concentrations of PPCPs ranged from <LOQ to 1455 ng/L, and untreated domestic wastewater was proposed as an important source of PPCPs in Huangpu River. Higher contamination levels of target PPCPs were detected in the lower reach (urban area) and dry season, compared to those in the upper reach (rural area) and wet season, respectively. The influence of rainfall on the occurrence of PPCPs was also extensively discussed in different regions along Huangpu River. At sampling sites in the rural area, similar or even lower concentrations of PPCPs were detected after rainfall; while increased concentrations of PPCPs were observed at most sampling sites, especially in the urban area, suggesting that overflow of untreated wastewater exceeding the capacity of wastewater treatment plants and leachates generated at temporary storage and transfer station of solid wastes might be the additional sources of PPCPs in the urban area in rainy days. These findings indicated that management of wastewater or/and solid wastes was more important to solve the problem of PPCPs contamination in the urban river of megacity. [ABSTRACT FROM AUTHOR]