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Molecular hydrides of divalent ytterbium supported by a macrocyclic ligand: synthesis, structure and olefin hydrofunctionalization catalysis.
- Source :
-
Chemical Communications . 10/14/2018, Vol. 54 Issue 80, p11280-11283. 4p. - Publication Year :
- 2018
-
Abstract
- Bis(triphenylsilyl) and dibenzyl ytterbium(ii) complexes supported by the macrocyclic polyamine ligand Me4TACD (1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) reacted with H2 to give the cationic ytterbium hydrides [(Me4TACD)2Yb2(μ2-H)(2+n)](2−n)+ (n = 0, 1). The hydrides catalyzed the H2/D2 isotope exchange as well as hydrogenation and hydrosilylation of 1-hexene. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MACROCYCLIC compounds
*ALKENES
YTTERBIUM isotopes
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 54
- Issue :
- 80
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 132151227
- Full Text :
- https://doi.org/10.1039/c8cc05152f