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Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment.
- Source :
-
Russian Journal of Coordination Chemistry . Oct2018, Vol. 44 Issue 10, p596-603. 8p. - Publication Year :
- 2018
-
Abstract
- Abstract: 1,10-Phenanthroline (Phen) adducts [M(L)Phen] in copper(II), cobalt(II), and zinc(II) chelates based on N,N,O-tridentate tosylamino-functionalized pyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 3-methyl-1-phenyl-4-formylpyrazol-5-ol, were obtained by electrosynthesis. The composition and structure of the mixed-ligand complexes were confirmed by elemental analysis, IR spectroscopy, and magnetochemical measurements. The structures of azomethine H2L and mixed-ligand copper(II) complex were determined by X-ray diffraction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 44
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 132187930
- Full Text :
- https://doi.org/10.1134/S1070328418100032