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Fast Exfoliation and Functionalisation of Two‐Dimensional Crystalline Carbon Nitride by Framework Charging.
- Source :
-
Angewandte Chemie . 9/24/2018, Vol. 130 Issue 39, p12838-12842. 5p. - Publication Year :
- 2018
-
Abstract
- Two‐dimensional (2D) layered graphitic carbon nitride (gCN) nanosheets offer intriguing electronic and chemical properties. However, the exfoliation and functionalisation of gCN for specific applications remain challenging. We report a scalable one‐pot reductive method to produce solutions of single‐ and few‐layer 2D gCN nanosheets with excellent stability in a high mass yield (35 %) from polytriazine imide. High‐resolution imaging confirmed the intact crystalline structure and identified an AB stacking for gCN layers. The charge allows deliberate organic functionalisation of dissolved gCN, providing a general route to adjust their properties. [ABSTRACT FROM AUTHOR]
- Subjects :
- *GRAPHENE
*CHEMICAL reactions
*PHOTOCATALYSIS
*CRYSTAL structure
*TRIAZINES
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 130
- Issue :
- 39
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 132309255
- Full Text :
- https://doi.org/10.1002/ange.201800875