Variations and sources of nitrous acid (HONO) during a severe pollution episode in Beijing in winter 2016.

Abstract HONO is an important precursor of OH radical and plays a key role in atmospheric chemistry, but its source and formation mechanism remain uncertain, especially during complex atmospheric pollution processes. In this study, HONO mixing ratios were measured by a custom-made instrument during a severe pollution event from 16 to 23 December 2016, at an urban area of Beijing. The measurement was divided into three periods: I (haze), II (severe haze) and III (clean), according to the levels of PM 2.5. This pollution episode was characterized by high levels of NO (75 ± 39 and 94 ± 40 ppbV during periods I and II, respectively) and HONO (up to 10.7 ppbV). During the nighttime, the average heterogeneous conversion frequency during the two haze periods were estimated to be 0.0058 and 0.0146 h−1, and it was not the important way to form HONO. Vehicle emissions contributed 52% (±16)% and 40% (±18)% to ambient HONO at nighttime during periods I and II. The contribution of homogeneous reaction of NO with OH should be reconsidered under high-NO x conditions and could be noticeable to HONO sources during this pollution event. Furthermore, HONO was positively correlated with PM 2.5 during periods I and II, suggesting a potential chemical link between HONO and haze particles. Graphical abstract Unlabelled Image Highlights • High HONO concentrations were observed in a severe pollution episode in Beijing. • The NO 2 conversion was not an important pathway to form HONO at nighttime. • Direct emissions could be critical to the observed HONO. • The homogeneous reaction could be a noticeable HONO source. • Good relation of HONO with PM 2.5 implied a chemical link between HONO and PM 2.5. [ABSTRACT FROM AUTHOR]