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Synthesis and structure of a novel Pd(0)–Pd(IV)–Pd(IV)–Pd(0) mixed-valence complex
- Source :
-
Inorganic Chemistry Communications . Jun2004, Vol. 7 Issue 6, p737-740. 4p. - Publication Year :
- 2004
-
Abstract
- The interaction of PdCl2(PhCN)2 with 1,2-[PhP(H)CH2CH2CH2P(Ph)CH2]2C6H4, generated in situ from the reduction of the corresponding phosphine oxide with LiAlH4 in the presence of Me3SiCl, gave a complex mixture, from which a di- and a tetra-nuclear palladium complex 1 and 2 whose solid state structures were ascertained by X-ray crystallography, were isolated. A novel Pd(0)–Pd(IV)–Pd(IV)–Pd(0) mixed-valence structure was observed in complex 2. [Copyright &y& Elsevier]
- Subjects :
- *CRYSTALLOGRAPHY
*HYDROGEN-ion concentration
*PHOSPHORUS compounds
*PALLADIUM
Subjects
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 7
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 13237416
- Full Text :
- https://doi.org/10.1016/j.inoche.2004.04.004