Back to Search
Start Over
Visible‐Light‐Catalyzed Phosphonation‐Annulation: an Efficient Strategy to Synthesize β‐Phosphonopyrrolidines and β‐Phosphonolactones.
- Source :
-
Chinese Journal of Chemistry . Nov2018, Vol. 36 Issue 11, p1052-1058. 7p. - Publication Year :
- 2018
-
Abstract
- A new type of phosphine radical precursor for C—P bond formation has been developed and successfully used in visible‐light‐catalyzed phosphonation‐annulation of unsaturated sulfonamides and carboxylic acids. The catalytic process is simple and green accessible, and no additional oxidant or base is needed. Mechanistic studies suggest that the reaction proceeds via a single electron transfer pathway. A new type of phosphine radical precursor for C—P bond formation has been developed and successfully used in visible‐light‐catalyzed phosphonation‐annulation of unsaturated sulfonamides and carboxylic acids. The catalytic process is simple and green accessible, and no additional oxidant or base is needed. Mechanistic studies suggest that the reaction proceeds via a single electron transfer pathway. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOSPHINES
*HETEROCYCLIC compounds
*ANNULATION
*PHOTOCATALYSIS
*CATALYTIC activity
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 36
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 132394101
- Full Text :
- https://doi.org/10.1002/cjoc.201800360