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Synthesis of mesoporous-zeolite materials using Beta zeolite nanoparticles as precursors and their catalytic performance in m-xylene isomerization and disproportionation.
- Source :
-
Applied Catalysis A: General . Nov2018, Vol. 568, p148-156. 9p. - Publication Year :
- 2018
-
Abstract
- Graphical abstract Highlights • Microporous/mesoporous materials were prepared using Beta nanozeolite precursors of varying crystallinity. • Zeolite precursors quenching by acid followed by hydrothermal treatment raises mesopore volume preserving chemical properties. • Adding Beta precursors to a gel containing non–ionic surfactant renders a mixture of preformed Beta nanocrystals and SBA–15. • Beta precursors treatments hardly modify p/o and i/d selectivities in m–xylene isomerization/disproportionation. Abstract Hierarchical Beta nanozeolites with the properties of both Beta nanozeolite and mesoporous material were prepared by two different methods: (1) Direct Hydrothermal Method (DHM) by the assembly of nanocrystals of preformed Beta seeds in the presence of the surfactant P123 under hydrothermal conditions, (2) Acidification of Beta seeds suspension (without the use of the mesopore directing agent). For the two methods, the effect of crystallization time of Beta nanozeolite precursor (seeds) was studied: 6, 12 and 24 h. The obtained materials were characterized using nitrogen sorption measurements, thermogravimetric analysis (TGA), X-ray diffraction (XRD), transmission electron microscopy (TEM), ammonia Temperature Programmed Desorption (NH 3 -TPD) and adsorption/desorption of pyridine monitored by FTIR. The characterization results show that acidification of Beta seeds suspension leads to best structured nano-Beta (Beta nanoparticles). However, with the DHM method physical mixtures of Beta nanoparticles and mesoporous SBA-15 phases were obtained. The m-xylene isomerization/disproportionation reaction in gas-phase was carried out over all the synthesized solids in order to explore their catalytic properties. It was found that the m-xylene conversion and isomerization/disproportionation ratio were closely related to the crystallization time of Beta zeolite precursors, mesopores creation in hierarchical Beta zeolite nanoparticles and the method used to produce the extra meso-porosity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0926860X
- Volume :
- 568
- Database :
- Academic Search Index
- Journal :
- Applied Catalysis A: General
- Publication Type :
- Academic Journal
- Accession number :
- 132627068
- Full Text :
- https://doi.org/10.1016/j.apcata.2018.10.005