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Supersonic beams of mixed gases: A method for studying cold collisions.
- Source :
-
Chemical Physics . Oct2018, Vol. 514, p150-153. 4p. - Publication Year :
- 2018
-
Abstract
- Abstract We show that collisions in a single supersonic molecular beam reach characteristic temperatures in the range of a few Kelvin. Experiments have been carried out for mixtures of H 2 and HD as well as HD and D 2 in a pulsed supersonic expansion. From the measured time-of-flight spectrum, we find that the high velocity edge of the distribution for both species is nearly coincident, but the average speed of the heavier species is slightly greater than the lighter one. By working in the few Kelvin regime, this relatively simple technique reduces the number of partial waves in the collision process, which allows the observation of collision resonances. Additionally, copropagation of scattering partners in a single molecular beam precisely defines the direction of their relative velocity vector, which is essential for the study of stereodynamics. [ABSTRACT FROM AUTHOR]
- Subjects :
- *MOLECULAR beams
*SUPERSONIC compressors
*VELOCITY
*RESONANCE
*SCATTERING (Physics)
Subjects
Details
- Language :
- English
- ISSN :
- 03010104
- Volume :
- 514
- Database :
- Academic Search Index
- Journal :
- Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 132687982
- Full Text :
- https://doi.org/10.1016/j.chemphys.2018.02.017