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3D CNTs-threaded N-doped hierarchical porous carbon hybrid with embedded Co/CoOx nanoparticles as efficient bifunctional catalysts for oxygen electrode reactions.
- Source :
-
Electrochimica Acta . Dec2018, Vol. 292, p707-717. 11p. - Publication Year :
- 2018
-
Abstract
- Abstract Developing an efficient non-precious metal catalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) in regenerative energy conversion and storage devices is very imperative but still challenging. Herein, a three-dimensional (3D) hierarchical porous Co/CoO x nanoparticles embedded N-doped carbon hybrid threaded with carbon nanotubes (Co/CoO x @NC-CNTs) was prepared via in situ threading CNTs through ZIF-67 polyhedron and a succedent carbonation process. Compared to those of commercial electrocatalysts (Pt/C and RuO 2), the as-prepared hybrid showed comparable electrocatalytic activity with positive ORR half-wave potential (E 1/2) of 0.836 V, low OER potential (E j=10 = 1.62 V), good methanol tolerance and excellent electrocatalytic stability. Moreover, the small overpotential difference value (Δ E = E j=10 - E 1/2) of 0.784 V is competitive to those of recent reported outstanding bifunctional oxygen electrocatalysts. The high electrocatalytic properties of the Co/CoO x @NC-CNTs hybrid are attributed to the synergistic effect of high surface area, desirable pore structure and reasonable chemical composition. Graphical abstract A 3D hierarchical porous Co/CoO x embedded N-doped carbon hybrid threaded with carbon nanotubes was prepared as high efficient bifunctional catalysts for oxygen electrode reactions. Image 1 [ABSTRACT FROM AUTHOR]
- Subjects :
- *PRECIOUS metals
*NITROGEN
*OXYGEN electrodes
*ELECTRODE reactions
Subjects
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 292
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 132919676
- Full Text :
- https://doi.org/10.1016/j.electacta.2018.10.001