Optimisation of high-temperature heat pump cascades with internal heat exchangers using refrigerants with low global warming potential.

Abstract High-temperature heat pumps (HTHPs) based on vapour compression can be used for industrial low-grade waste heat valorisation, which can aid in mitigating climate change. Currently, the performance of HTHPs operating at high-temperatures lifts is limited; therefore, advanced configurations become an opportunity for their utilisation. This paper presents an HTHP cascade with configurations of internal heat exchangers (IHXs) that uses low GWP refrigerants in both high-stage (HS) (HCFO-1233zd(E), HFO-1336mzz(Z), HCFO-1224yd(Z), and pentane) and low-stage (LS) (HFO-1234yf, HFO-1234ze(E), butane, isobutane, and propane) cycles. Prior to the analysis and presentation of results, an optimisation of the operating conditions is performed based on intermediate temperature and IHX effectiveness in both stage cycles. Results indicate that butane and isobutane appear to be the most convenient working LS fluids from the point of view of coefficient of performance (COP). The highest system performance is obtained using pentane and HFO-1336mzz(Z) in the HS cycle. Compared to third-generation refrigerants (HFC-245fa/HFC-134a), a slight COP improvement is obtained using HCFO-1233zd(E), and HCFO-1224yd(Z). A comparable or even lower volumetric flow rate at the HS compression suction is also observed. The use of pentane/butane achieved maximum COP (3.15), which is a 13% improvement compared to COP obtained when HFC-245fa/HFC-134a is employed. Highlights • A high-temperature heat pump cascade with the IHXs is proposed and optimised. • Synthetic and natural refrigerants with low GWPs are proposed for both stages. • The higher effectiveness of both IHXs in similar proportions increases total COP. • Pentane/butane presents maximum COP and minimum HCFO-1224yd(Z)/HFO-1234yf. • A few refrigerant pairs are comparable with HFC-245fa/HFC-134a in the stages of V ˙ s u c . [ABSTRACT FROM AUTHOR]