Constructing Successive Active Sites for Metal‐free Electrocatalyst with Boosted Electrocatalytic Activities Toward Hydrogen Evolution and Oxygen Reduction Reactions.

As well known, heteroatom doped carbon material served as metal‐free electrocatalyst for hydrogen evolution (HER) and oxygen reduction reactions (ORR) particularly relies on the heteroatom doping level. Here, we report a 3D porous nitrogen doped carbon (PNC) electrocatalyst with superior HER and ORR electrocatalytic activities derived from the calcination of the discarded cigarette butt and dicyandiamide possessing a high nitrogen content (20 at%). PNC electrocatalyst only demands 143 mV versus RHE to achieve 10 mA cm−2 ascribed to the high nitrogen percentile in PNC electrocatalyst favorable for constructing successive active centers contributing to efficiently catalyzing HER. Ignorable degradation in HER activity observed after 10000 potential cycles as well as undetectable decay in HER performance recorded after 12 h operation indicate high stability of PNC electrocatalyst. Meanwhile, half‐wave potential of PNC electrocatalyst reaches 0.81 V versus RHE in 1 M KOH electrolyte. Additionally, stable ORR activity attained after 1000 potential cycles is indicative of high stability. A comparably high zinc‐air battery performance with maximum power density of 66 mW cm−2 is achieved by PNC electrocatalyst. This study highlights the importance of nitrogen doping level in metal‐free electrocatalyst for boosting HER and ORR activities. What? No metal! A 3D porous nitrogen doped carbon (PNC) electrocatalyst with superior HER and ORR electrocatalytic activities derived from the calcination of the discarded cigarette butt and dicyandiamide possessing a high nitrogen content (20 at%). [ABSTRACT FROM AUTHOR]