One-pot synthesis of arginine modified hydroxyapatite carbon microsphere composites for efficient removal of U(VI) from aqueous solutions.

Graphical abstract A novel arginine modified hydroxyapatite carbon microsphere (C@HAp/Arg) composite were synthesized by a facile and green method and exhibited superior adsorption efficiency for removal of U(VI). Abstract Uranium was not only the main source of nuclear energy but also one of the long-lived radionuclide. Herein, a novel arginine modified hydroxyapatite carbon microsphere composites (defined as C@HAp/Arg) obtained promptly via a one-step mild hydrothermal method, was applied to remove U(VI) from aqueous solutions. Based on the characterization of transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), the synthesized C@HAp/Arg presented globular morphology and abundant functional groups (e.g., COO−), which were beneficial to its combination with U(VI). The interaction mechanism and removal capability of U(VI) on C@HAp/Arg were studied by batch adsorption technique and spectroscopy analysis. The results implied that U(VI) can form strong surface complexes on C@HAp/Arg. The kinetics adsorption of U(VI) followed pseudo-second-order kinetic model with high removal efficiency (∼95% within 5 h at pH 5.0). The adsorption isotherms were well fitted by Langmuir model, implying that U(VI) uptake on C@HAp/Arg was monolayer coverage. It was found that the maximum adsorption capacities of CSs, C@HAp and C@HAp/Arg toward U(VI) were calculated to be 23.16, 72.09 and 569.66 mg/g, respectively, at 298.15 K and pH 5.0, and thermodynamic parameters revealed that the adsorption processes of U(VI) were spontaneous and endothermic. In addition, effect of co-existed ions and CO 3 2− concentrations demonstrated that U(VI) adsorption on C@HAp/Arg was weakly interfered by foreign ions and carbonate concentrations. More importantly, the adsorption performance of U(VI) on C@HAp/Arg was still over ∼87% after five cycles. Therefore, it was noted that the versatile C@HAp/Arg could be potentially used as a powerful building block for the enrichment and disposal of U(VI) from aqueous solutions, which could efficiently reduce the potential toxicity of U(VI) in the U(VI)-contaminated water. [ABSTRACT FROM AUTHOR]