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Competing Crystallization between Lanthanide and Actinide in Acidic Solution Leading to Their Efficient Separation.
- Source :
-
Chinese Journal of Chemistry . Jan2019, Vol. 37 Issue 1, p53-57. 5p. - Publication Year :
- 2019
-
Abstract
- Summary of main observation and conclusion: We present a new method for generating europium oxalate compounds by decomposing of N‐methyl 2‐pyrrolidone in HNO3 media. The reaction exhibits high selectivity towards Eu3+ over UO22+, which suggests that these conditions could be applied to a selective crystallization based separation system for trivalent lanthanides and hexavalent actinides. In this work, a new method for the separation of trivalent Eu3+ and hexavalent UO22+ in initial high‐acidity HNO3 solution is presented. N‐Methyl 2‐pyrrolidone was added in the HNO3 solution where Eu3+ and UO22+ coexisted, then the solution was heated. Eu3+ will react with oxalic acid and dimethylamine produced by N‐methyl 2‐pyrrolidone and form compound NH2(CH3)2[Eu(C2O4)2(H2O)], while UO22+ remains in the solution. This method provide a new strategy for separation of trivalent Eu3+ and hexavalent UO22+. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CRYSTALLIZATION
*RARE earth metals
*ACTINIDE elements
*EUROPIUM
*OXALIC acid
Subjects
Details
- Language :
- English
- ISSN :
- 1001604X
- Volume :
- 37
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Chinese Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 133557880
- Full Text :
- https://doi.org/10.1002/cjoc.201800468