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Solvent‐free ring‐opening polymerization of lactones with hydrogen‐bonding bisurea catalyst.
- Source :
-
Journal of Polymer Science Part A: Polymer Chemistry . Jan2019, Vol. 57 Issue 2, p90-100. 11p. - Publication Year :
- 2019
-
Abstract
- Development of effective organocatalysts for the living ring‐opening polymerization (ROP) of lactones is highly desired for the preparation of biocompatible and biodegradable polyesters with controlled microstructures and physical properties. Herein, a new class of hydrogen‐bond donating bisurea catalysts is reported for the ROP of lactones under solvent‐free conditions. ROP of lactones mediated by the bisurea/7‐methyl‐1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (MTBD) catalyst exhibits a living/controlled manner, affording the polymers and copolymers with the well‐defined structure, predictable molecular weight, narrow molecular weight distribution, and high selectivity for monomer at low catalyst loadings at ambient temperature. The possible mechanism of bisurea/MTBD‐catalyzed ROP of lactones is proposed, in which the bisurea activates the carbonyl group of lactones while MTBD facilitates the nucleophilic attack of the initiating/propagating alcohol by hydrogen bonding. Moreover, the poly(ε‐caprolactone‐co‐δ‐valerolactone) [P(CL‐co‐VL)] random copolymers with various compositions were synthesized using the bisurea/MTBD catalyst. The measurements of thermal properties and crystalline structure demonstrate that the CL and VL units are cocrystallized in the crystalline phase of P(CL‐co‐VL) copolymers. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019, 57, 90–100 A new class of hydrogen‐bonding bisurea catalysts is reported for the ring‐opening polymerization (ROP) of lactones under solvent‐free conditions. ROP of lactones mediated by the bisurea/7‐methyl‐1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene catalyst exhibits a living/controlled manner, affording the polymers and copolymers with the well‐defined structure, predictable molecular weight, and narrow molecular weight distribution at low catalyst loadings at ambient temperature. [ABSTRACT FROM AUTHOR]
- Subjects :
- *POLYMERIZATION
*CATALYSTS
*CHEMICAL reactions
*CATALYSIS
*HYDROGEN bonding
Subjects
Details
- Language :
- English
- ISSN :
- 0887624X
- Volume :
- 57
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Polymer Science Part A: Polymer Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 133581448
- Full Text :
- https://doi.org/10.1002/pola.29268