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Synthesis and Structural Characterization of a Nickel Coordination Polymer Based on 4-(1H-Imidazol-1-yl)phenyl)methanone with Phthalic Acid.
- Source :
-
Crystallography Reports . Dec2018, Vol. 63 Issue 7, p1120-1123. 4p. - Publication Year :
- 2018
-
Abstract
- Abstract: A nickel coordination polymer with V-shaped ligands, {[(L1)2Ni(H2O)2] · 2(C8H5O4)}n, (L1 = 4-(1H-imidazol-1-yl)phenyl)methanone) has been synthesized under the solvothermal conditions. The structure has been determined by the single-crystal X-ray diffraction analysis and characterized by the infrared spectroscopy and elemental analysis. The crystal is crystallized in the monoclinic sp. gr. P21/c with the unit cell parameters a = 15.6387(3) Å, b = 8.0526(2) Å, c = 24.4791(6) Å, and β = 129.2350(10)°, Z = 2. The adjacent [Ni(H2O)2] units are linked by two bridging L1 ligands to form 1D looped chains, which are extended by the hydrogen bonds to yield a 3D framework. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10637745
- Volume :
- 63
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Crystallography Reports
- Publication Type :
- Academic Journal
- Accession number :
- 133588705
- Full Text :
- https://doi.org/10.1134/S1063774518070246