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Development of supramolecular shape-memory polyurethanes based on Cu(II)-pyridine coordination interactions.
- Source :
-
Journal of Materials Science . Mar2019, Vol. 54 Issue 6, p5136-5148. 13p. 6 Diagrams, 1 Chart, 7 Graphs. - Publication Year :
- 2019
-
Abstract
- Shape-memory polymers with supramolecular switch have received increasing attention. This study reports the synthesis and characterization of supramolecular shape-memory polyurethane based on Cu(II)-pyridine coordination, obtained by mixing pyridine containing polyurethane with CuCl2. The results show that there are strong metal-ligand coordination interactions formed between Cu(II) and the pyridine ring in a series of CuCl2-doped polyurethane samples. The Cu(II)-pyridine coordination plays a crucial role in the enhanced physical netpoints for outstanding shape-memory properties. Indeed, the so-synthesized CuCl2-doped polyurethane exhibits not only a rapid tensile shape recovery but also excellent crimp shape recovery. The CuCl2-doped polyurethane containing suitable metal-ligand coordination interactions shows more than 99% shape fixation and more than 95% shape recovery. Our findings promote further applications of shape-memory polymers in multiple engineering fields. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00222461
- Volume :
- 54
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Journal of Materials Science
- Publication Type :
- Academic Journal
- Accession number :
- 133654626
- Full Text :
- https://doi.org/10.1007/s10853-018-3179-2