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Difference in physical properties of MAX-phase compounds Cr2GaC and Cr2GaN induced by an anomalous structure change in Cr2GaN.
- Source :
-
Intermetallics . Feb2019, Vol. 105, p39-43. 5p. - Publication Year :
- 2019
-
Abstract
- Abstract MAX-phase compounds with layered structure have been investigated extensively due to their excellent metallic and ceramic properties. Among them, Cr 2 GaC and Cr 2 GaN possess the same crystal structure and similar electronic structure, whereas Cr 2 GaN undergoes a spin-density-wave transition around 170 K but Cr 2 GaC is Pauli paramagnetism without any magnetic transition. To understand what make these happen, we studied the crystal structure between 300 and 35 K for both Cr 2 GaC and Cr 2 GaN. As the temperature decreases, the lattice constants (both a and c) decline monotonically in Cr 2 GaC, while an abnormal negative thermal expansion of c axis was observed below 170 K in Cr 2 GaN. The increase of c/a induced by abnormal increase of c leads to the enhancement of localization of Cr 2 N plane and causes more Cr-3 d electrons confinement in Cr 2 N plane of Cr 2 GaN. This further facilitates the reconstruction of density of states near the Fermi surface and even forms the Fermi surface nesting, resulting in the spin-density-wave transition as well as the abrupt changes of resistivity, specific heat, and density of carriers around 170 K in Cr 2 GaN. Graphical abstract We reported microtopography as well as temperature dependent resistivity, specific heat, and density of carriers in isostructural Cr 2 GaC and Cr 2 GaN, and there exists considerable differences. To make it clear, we investigated the changes of structure with temperature between 300 and 35 K in both Cr 2 GaC and Cr 2 GaN. The anomalous increase of lattice constant c and c/a ratio were observed around 170 K in Cr 2 GaN, which is the inducement of spin-density-wave and the origin of anomalous changes in resistivity, specific heat, and density of carriers in Cr 2 GaN. Therefore, the biggest difference between Cr 2 GaC and Cr 2 GaN is just an anomalous structure change of Cr 2 GaN. Image 1 Highlights • We firstly reported the negative thermal expansion of c axis below 170 K in Cr 2 GaN, leading to an anomalous increase of c / a. • Differences were observed in microtopography, resistivity, specific heat, and density of carriers between Cr 2 GaC and Cr 2 GaN. • Anomalous structure changes at 170 K cause the reconstruction of density of states near Fermi surface in metallic Cr 2 GaN. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09669795
- Volume :
- 105
- Database :
- Academic Search Index
- Journal :
- Intermetallics
- Publication Type :
- Academic Journal
- Accession number :
- 133736796
- Full Text :
- https://doi.org/10.1016/j.intermet.2018.11.008