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N-Sulfonyl acetylketenimine as a highly reactive intermediate for synthesis of N-Aroylsulfonamides.
- Source :
-
Tetrahedron . Jan2019, Vol. 75 Issue 3, p381-386. 6p. - Publication Year :
- 2019
-
Abstract
- Abstract A highly reactive intermediate N- sulfonyl acetylketenimine was generated from an ynone-participated CuAAC/ring-opening method. Its unique structure allowed it to react with aryl carboxylic acids to give N -aroylsulfonamides via a novel Mumm-type rearrangement. Graphical abstract Image 1 [ABSTRACT FROM AUTHOR]
- Subjects :
- *CARBOXYLIC acids
*CLICK chemistry
*SULFONYL compounds
*KETENIMINES
Subjects
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 75
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 133749532
- Full Text :
- https://doi.org/10.1016/j.tet.2018.12.005