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A novel α-Fe2O3@g-C3N4 catalyst: Synthesis derived from Fe-based MOF and its superior photo-Fenton performance.
- Source :
-
Applied Surface Science . Mar2019, Vol. 469, p331-339. 9p. - Publication Year :
- 2019
-
Abstract
- Graphical abstract Highlights • α-Fe 2 O 3 @g-C 3 N 4 catalyst was synthesized by a facile co-calcination. • It showed excellent photo-Fenton catalytic activity in a wide range of pH. • The high catalytic activity of the catalyst is due to its Z-scheme heterostructure. Abstract Fabricating heterojunction catalysts is a promising strategy for improving the performance in heterogeneous photo-Fenton reaction (PFR). Herein, a Z-scheme heterostructured α-Fe 2 O 3 @g-C 3 N 4 catalyst was successfully synthesized through the co-calcination of melamine and Fe-based MOF. The characterization results demonstrated that α-Fe 2 O 3 nanoparticles anchored on the surface of g-C 3 N 4 successfully. The degradation of tetracycline (TC) in visible-light/H 2 O 2 system was adopted to evaluate the photo-Fenton activity of the catalysts. About 92% of TC was degraded by the optimum composite FOCN-0.45 in 60 min; the degradation rate (0.042 min−1) of TC by the FOCN-0.45 is 6, 7 and 14 times higher than that by pristine MIL-53 (Fe) (0.007 min−1), α-Fe 2 O 3 (0.006 min−1) and g-C 3 N 4 (0.003 min−1), respectively. The prepared FOCN-0.45 composite exhibited excellent performance and high stability in a wide range of pH value. The promoted photo-Fenton catalytic efficiency benefited from the Z-scheme heterojunctions of α-Fe 2 O 3 @g-C 3 N 4 , which enhanced the separation ability of photo-generated charge carriers and increased the electrons that participated in Fe2+/Fe3+ cycle. The boosting OH radicals degraded organic pollutants as main reactive radicals. This work presents a feasible path to design and synthesize heterogeneous photo-Fenton catalysts for the removal of organic pollutants. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01694332
- Volume :
- 469
- Database :
- Academic Search Index
- Journal :
- Applied Surface Science
- Publication Type :
- Academic Journal
- Accession number :
- 133765902
- Full Text :
- https://doi.org/10.1016/j.apsusc.2018.10.183