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A facile slow-gel method for bulk Al-doped carboxymethyl cellulose aerogels with excellent flame retardancy.
- Source :
-
Carbohydrate Polymers . Mar2019, Vol. 207, p352-361. 10p. - Publication Year :
- 2019
-
Abstract
- Highlights • Bulk Al-doped carboxymethyl cellulose aerogels were fabricated via a facile slow-gel method and freeze-drying technology. • Compared with pure silica aerogels, the Al-doped carboxymethyl cellulose aerogels possed better weight-bearing capacity. • The Al-doped CMC aerogels exhibited excellent flame retardancy and could be rated V-0 regarding UL-94 testing. Abstract Bulk Al-doped carboxymethyl cellulose aerogels were obtained via a facile slow-gel method and freeze-drying technology. In this method, the cross-linker Al3+ was released slowly and completely with enough d -(+)-gluconic acid δ -lactone as a sustained-release agent. Depended on controlled releasing of Al3+, the reaction speed between Al3+ and carboxyl groups was controlled and Al3+ was well-distributed in the aerogels. The coordination type between Al3+ and carboxymethyl cellulose was the bidentate bridging coordination. By adjusting the amount of Al3+ and the degree of substitution of carboxymethyl cellulose, interconnected network and closely packed sheet-like structure presented, respectively. According to the nitrogen adsorption-desorption isotherms, the aerogels were a kind of mesoporous material with pore blocking or cavitation. In addition, the aerogels exhibited outstanding weight-bearing capacity and excellent flame retardancy. This work provided a valuable reference for doping metal ions into polysaccharide aerogels and expanding the application fields of aerogels. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CARBOXYMETHYLATION
*AEROGELS
*CERAMIC materials
*CARBOXYL group
*POLYSACCHARIDES
Subjects
Details
- Language :
- English
- ISSN :
- 01448617
- Volume :
- 207
- Database :
- Academic Search Index
- Journal :
- Carbohydrate Polymers
- Publication Type :
- Academic Journal
- Accession number :
- 133781160
- Full Text :
- https://doi.org/10.1016/j.carbpol.2018.11.089