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Novel synthesis of popcorn-like TiO2 light scatterers using a facile solution method for efficient dye-sensitized solar cells.
- Source :
-
Journal of Power Sources . Feb2019, Vol. 413, p384-390. 7p. - Publication Year :
- 2019
-
Abstract
- Abstract In this study, a facile solution method is proposed for synthesizing popcorn-like TiO 2 aggregations (P-TiO 2) as the light scatterers in the photoanode of DSSCs. This novel solution method is promising due to the less time and lower temperature required for carrying out the reaction, comparing to those for the conventional hydrothermal synthesis. The P-TiO 2 has the size of 300 nm and is composed of small nanoparticles with the size of 50 nm. Also, different from the common light scatterers, the P-TiO 2 has a special anatase phase which is beneficial for dye adsorption and charge transfer. The highest solar-to-electricity conversion efficiency of 7.56% is obtained for the DSSC with the photoanode composed of the commercial P90 TiO 2 dye-adsorption layer and the P-TiO 2 light scattering layer, due to the large surface area, highly active anatase nature, and the excellent light scattering ability for the home-made P-TiO 2. The results suggest that the photovoltaic performance of DSSCs can be efficiently improved by carefully designing the morphology of the TiO 2 nanostructure in the photoanode with large surface area and unique configuration to confine the incident light in the electrode for longer time. Graphical abstract Image 1 Highlights • Novel synthesis of Popcorn-like TiO 2 light scatterers. • High conversion efficiency is by light scattering layer. • High performance is due to well-defined structure. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SOLAR cells
*TITANIUM dioxide
*LIGHT scattering
*ANODES
*CHARGE transfer
Subjects
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 413
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 134184740
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2018.12.065