High temperature resistant polyimide/boron carbide composites for neutron radiation shielding.

Abstract Boron carbide (B 4 C) is an important type of neutron radiation shielding material with relatively high efficiency due to the high content of 10B element. Incorporation of B 4 C particles into polymer to prepare high-performance neutron radiation shielding material has become more and more important for the safe operation of nuclear power in the defense industry and nuclear power plant. The polyimide/B 4 C composite films with different micro-sized B 4 C contents were successfully prepared by in-situ polymerization. Silane coupling agent KH550 was employed to functionalize B 4 C particles to improve the dispersion of B 4 C particles in the polyimide matrix with strengthened interfacial interaction. As shown that the micro-sized B 4 C functional particles can be well dispersed in the BPDA/ODA polyimide matrix. With the B 4 C content increase, thermal stability of the polyimide/B 4 C composite films can be significantly improved, even mechanical properties partly declined. Meanwhile, the polyimide/B 4 C composite films exhibit good thermal neutron radiation shielding properties. The neutron permeability I/I 0 changes exponentially with the change of B 4 C content. When the B 4 C content is increased to 30 wt%, the polyimide/B 4 C composite films show optimum properties combination with thermal decomposition temperature (T d 10) of 622 °C, neutron permeability (I/I 0) of 0.24 (800 μm in thickness), and tensile strength of 406 MPa. The composite thus shows great potential for use in applications which require materials with high thermal stability and neutron radiation shielding ability, such as fusion reactor system and nuclear waste disposal. [ABSTRACT FROM AUTHOR]