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Crystallization of magnetic particles in nNa2O-9SrO-6Fe2O3-8B2O3 (n = 1 and 4) glasses.
- Source :
-
Journal of Magnetism & Magnetic Materials . Apr2019, Vol. 476, p311-316. 6p. - Publication Year :
- 2019
-
Abstract
- Highlights • Crystallization of magnetic particles from Na 2 O-SrO-Fe 2 O 3 -B 2 O 3 glasses is studied. • Increase of sodium oxide content leads to decrease of crystallization temperatures. • Crystallization of 4 nm maghemite nanoparticles is observed at low temperatures. • Hexaferrite morphology and properties are determined by annealing temperatures. Abstract Magnetic glass-ceramics with composition n Na 2 O-9SrO-6Fe 2 O 3 -8B 2 O 3 (n = 1 and 4) were prepared by fast quenching of the molten oxide mixtures and subsequent thermal treatment of the obtained glasses at 450–950 °C. The samples were investigated by differential thermal analysis, x-ray powder diffraction, electron microscopy, and SQIUD magnetometry. Increasing of the sodium oxide content leads to a significant decrease of the glass transition, devitrification, and melting temperatures. Just above the glass transition temperature (525 °C for n = 1 and 430 °C for n = 4) superparamagnetic γ-Fe 2 O 3 nanoparticles precipitate, which, at elevating annealing temperature, are substituted by thin hexaferrite nanoplatelets with coercivities of 2000–4000 Oe; the annealing at higher temperatures results in crystallization of the submicron hexaferrite particles with a coercivity of up to 6000 Oe. Thus the glass-ceramics are highly applicable sources of non-sintered nanoparticles with various morphologies and magnetic properties. [ABSTRACT FROM AUTHOR]
- Subjects :
- *GLASS
*CRYSTALLIZATION
*ANNEALING of glass
*MAGNETIC particles
*ELECTRON microscopy
Subjects
Details
- Language :
- English
- ISSN :
- 03048853
- Volume :
- 476
- Database :
- Academic Search Index
- Journal :
- Journal of Magnetism & Magnetic Materials
- Publication Type :
- Academic Journal
- Accession number :
- 134296428
- Full Text :
- https://doi.org/10.1016/j.jmmm.2018.12.083