Insight into CaO2-based Fenton and Fenton-like systems: Strategy for CaO2-based oxidation of organic contaminants.

Graphical abstract Highlights • The oxidation capabilities of CaO 2 /Fe(II) and CaO 2 /Fe(III) systems were compared. • Fe(II)/Fe(III), H 2 O 2 , HO, and intermediate products are evaluated in both systems. • An optimal implementation strategy for the CaO 2 application was proposed. • The strategy derived from benzene degradation works for TCE degradation. Abstract This study conducted a comparison of the CaO 2 -based Fenton (CaO 2 /Fe(II)) and Fenton-like (CaO 2 /Fe(III)) systems on their benzene degradation performance. The H 2 O 2 , Fe(II), Fe(III), and HO variations were investigated during the benzene degradation. Although benzene has been totally removed in the two systems, the variation patterns of the investigated parameters were different, leading to different benzene degradation patterns. In terms of the Fe(II)/Fe(III) conversion, the CaO 2 /Fe(II) and CaO 2 /Fe(III) systems were actually inseparable and had the inherent mechanism relationships. For the CaO 2 /Fe(III) system, the initial Fe(III) must be converted to Fe(II), and then the consequent Fenton reaction could be later developed with the regenerated Fe(II). Moreover, some benzene degradation intermediates could have the ability to facilitate the transformation of the Fe(III) to Fe(II) without the classic H 2 O 2 -associated propagation reactions. By varying the Fe(II) dosing method, an effective degradation strategy has been developed to take advantage of the two CaO 2 -based oxidation systems. The proposed strategy was further successfully tested in TCE degradation, therefore extending the potential for the application of this technique. [ABSTRACT FROM AUTHOR]