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Dioxygen activation with stable N-heterocyclic carbenes.
- Source :
-
Chemical Communications . 2/7/2019, Vol. 55 Issue 11, p1584-1587. 4p. - Publication Year :
- 2019
-
Abstract
- Dioxygen activation with both cyclic (amino)(alkyl)carbenes and di(amino)carbenes at ambient temperature is described. Theoretical studies suggest that electron rearrangement from the doubly filled σ orbital of carbene carbon to its vacant p orbital through the π* antibonding orbital of 3O2 can be considered for Ccarbene–O bond formation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DIOXYGENASES
*CARBENES
*CHEMICAL bonds
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 55
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 134404452
- Full Text :
- https://doi.org/10.1039/c8cc08911f