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A novel self-complementary three-dimensional inorganic network organized by H-bond dimers of inorganic chains — Synthesis and crystal structure of (C6H16N2)[Zn(HPO4)2].
- Source :
-
Canadian Journal of Chemistry . May2004, Vol. 82 Issue 5, p616-621. 6p. 3 Diagrams, 4 Charts. - Publication Year :
- 2004
-
Abstract
- A novel organic-templated zincophosphate, namely (C6H16N2)[Zn(HPO4)2], was hydrothermally synthesized and X-ray single-crystal structural analysis reveals that the anions [Zn(HPO4)2]2–, which have square-twisted chains containing corner-sharing four-rings of alternating ZnO4 and PO4 tetrahedra, are assemblied via self-complementary strong and symmetrical hydrogen-bonding R22(8) synthons between the phosphate groups into three-dimensional hydrogen bond frameworks featuring three-dimensional intersecting pseudochannels. The doubly protonated 2,5-dimethylpiperazinium cations are attached to the three-dimensional inorganic framework via N-H···O hydrogen bonds to strengthen the 3-D network. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROGEN bonding
*DIMERS
*PHOSPHATES
*POLYPHOSPHATES
*ANIONS
Subjects
Details
- Language :
- English
- ISSN :
- 00084042
- Volume :
- 82
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Canadian Journal of Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 13461185
- Full Text :
- https://doi.org/10.1139/V04-026