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Giant antiferromagnetic negative thermal expansion in (MnNiGe)1-x(MnCoSn)x compounds.
- Source :
-
Journal of Alloys & Compounds . Apr2019, Vol. 782, p881-886. 6p. - Publication Year :
- 2019
-
Abstract
- Abstract The large volumetric contraction effect presented by MnM'X (M' = Co, Ni; X = Ge, Si) during the martensitic (MA) transformation displays their potential applications in negative thermal expansion (NTE) field. In this work, we report the giant antiferromagnetic (AFM) NTE in (MnNiGe) 1- x (MnCoSn) x (0.02 ≤ x ≤ 0.1) compounds. When x = 0.02, 0.04, 0.06 and 0.1, their average linear NTE coefficients reach −48 ppm/K (220 K - 332 K), −96 ppm/K (174 K-280 K), −92 ppm/K (116 K-220 K) and −35 ppm/K (75 K-130 K), respectively. Moreover, the magnetization shows a descending tendency with increasing x from 0.02 to 0.1, which can be attributed to the more-antiparallel AFM ground state, suggesting their feasible applications in the magnetic environment. Highlights • Antiferromagnetic negative thermal expansions are obtained in (MnNiGe) 1- x (MnCoSn) x (0.02 ≤ x ≤ 0.1) compounds. • The (MnNiGe) 0.98 (MnCoSn) 0.02 compound shows a lower magnetostriction than the ferromagnetic Mn 0.98 CoGe compound. • The relatively high thermal conductivities are observed in (MnNiGe) 1- x (MnCoSn) x (x =0.02 and 0.3) compounds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 782
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 134687871
- Full Text :
- https://doi.org/10.1016/j.jallcom.2018.12.127