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Zintl-phase Eu2ZnSb2: A promising thermoelectric material with ultralow thermal conductivity.
- Source :
-
Proceedings of the National Academy of Sciences of the United States of America . 2/19/2019, Vol. 116 Issue 8, p2831-2836. 6p. - Publication Year :
- 2019
-
Abstract
- Zintl compounds are considered to be potential thermoelectric materials due to their "phonon glass electron crystal" (PGEC) structure. A promising Zintl-phase thermoelectric material, 2-1-2-type Eu2ZnSb2 (P63/mmc), was prepared and investigated. The extremely low lattice thermal conductivity is attributed to the external Eu atomic layers inserted in the [Zn2Sb2]2- network in the structure of 1-2-2-type EuZn2Sb2 (P3m1), as well as the abundant inversion domain boundary. By regulating the Zn deficiency, the electrical properties are significantly enhanced, and the maximum ZT value reaches ~1.0 at 823 K for Eu2Zn0.98Sb2. Our discovery provides a class of Zintl thermoelectric materials applicable in the mediumtemperature range. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00278424
- Volume :
- 116
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Proceedings of the National Academy of Sciences of the United States of America
- Publication Type :
- Academic Journal
- Accession number :
- 134840651
- Full Text :
- https://doi.org/10.1073/pnas.1819157116