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Synthesis of Functionalized Cyclobutane‐Fused Naphthalene Derivatives via Cascade Reactions of Allenynes with tert‐Butyl Nitrite.
- Source :
-
Advanced Synthesis & Catalysis . 3/15/2019, Vol. 361 Issue 6, p1271-1276. 6p. - Publication Year :
- 2019
-
Abstract
- A novel synthesis of cyclobutanol‐fused 2‐nitronaphthalen‐1‐ols and nitrocyclobutane‐fused naphthalene‐1,2‐diones through cascade reactions of benzene‐linked allenynes with tert‐butyl nitrite is presented. The formation of the title compounds involves a tandem process including allenyne [2+2] cycloaddition, radical addition onto the in situ formed cyclobutenyl moiety followed by radical coupling/oxidation. Interestingly, different kinds of functionalized naphthalene derivatives could be obtained selectively from the same substrates, and the selectivity was easily controlled by finely tuning the reaction conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- *NAPHTHALENE derivatives
*NITRITES
Subjects
Details
- Language :
- English
- ISSN :
- 16154150
- Volume :
- 361
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Advanced Synthesis & Catalysis
- Publication Type :
- Academic Journal
- Accession number :
- 135349803
- Full Text :
- https://doi.org/10.1002/adsc.201801439