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Rh(III)-Catalyzed Annulation of Boc-Protected Benzamides with Diazo Compounds: Approach to Isocoumarins.

Authors :
Dong, Guangyu
Li, Chunpu
Liu, Hong
Source :
Molecules. Mar2019, Vol. 24 Issue 5, p937. 1p.
Publication Year :
2019

Abstract

A mild rhodium-catalyzed annulation of Boc-protected benzamides with diazo compounds via C−C/C−O bond formation has been explored. In the presence of [Cp*RhCl2]2, AgSbF6 and Cs2CO3, Boc-protected benzamides can be effectively annulated to yield isocoumarins in 0.5–2 h. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14203049
Volume :
24
Issue :
5
Database :
Academic Search Index
Journal :
Molecules
Publication Type :
Academic Journal
Accession number :
135380986
Full Text :
https://doi.org/10.3390/molecules24050937