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Ni(II), Pd(II) and Pt(II) complexes with SacNac tridentate ligand.
- Source :
-
Polyhedron . Apr2019, Vol. 162, p207-218. 12p. - Publication Year :
- 2019
-
Abstract
- Graphical abstract Neutral and cationic nickel, palladium and platinum complexes containing a new N,N,S-tridentate ligand have been prepared and characterized. The structure of the ligand and eight complexes was determinate by X-ray crystallographic analysis. Ligand can be both mono- or di-deprotonated under mild reaction conditions. Studies in Heck reaction and antiproliferative activities are reported. Abstract Organometallic and coordination nickel, palladium and platinum complexes, neutral and cationic, with general formula [M(κ3-SacNac)X] and [M(κ3-SacNac)L′][BPh 4 ] (where M = Ni, Pd and Pt, X = Me, Cl, 1 – 6 ; M = Ni, X = N 3 , SMe, 7 – 8 ; M = Pd, X = I, 13 ; M = Ni and Pd, L′ = PPh 3 , 9 – 10 ; M = Ni and Pt, X = PMe 3 , dmso, 11 – 12) containing a new SacNac N,N,S-tridentate ligand [C 6 H 5 (S)CCH 2 C(N-CH 2 CH 2 NHC 6 H 5)CH 3 ] were synthetized and obtained as microcrystalline solids. Compounds 2 – 13 were fully characterized by elemental analysis, IR, 1D and 2D NMR spectroscopy. The structure of the ligand and eight complexes was determined by X-ray crystallographic analysis. The ligand can be both mono- or bi-deprotonated under mild reaction conditions. Results in Heck reaction and antiproliferative activities are reported. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PRECIOUS metals
*PLATINUM
*HECK reaction
*NUCLEAR magnetic resonance spectroscopy
Subjects
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 162
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 135428273
- Full Text :
- https://doi.org/10.1016/j.poly.2019.01.021