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Photoelectrochemical C−H Alkylation of Heteroarenes with Organotrifluoroborates.
- Source :
-
Angewandte Chemie International Edition . 3/26/2019, Vol. 58 Issue 14, p4592-4595. 4p. - Publication Year :
- 2019
-
Abstract
- A photoelectrochemical method for the C−H alkylation of heteroarenes with organotrifluoroborates has been developed. The merger of electrocatalysis and photoredox catalysis provides a chemical oxidant‐free approach for the generation and functionalization of alkyl radicals from organotrifluoroborates. A variety of heteroarenes were functionalized using primary, secondary, and tertiary alkyltrifluoroborates with excellent regio‐ and chemoselectivity. A radical approach: A photoelectrochemical method has been developed for the C−H alkylation of heteroarenes with organotrifluoroborates under oxidant‐free conditions. A variety of heteroarenes can be functionalized with primary, secondary, and tertiary alkyl groups with excellent regio‐ and chemoselectivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 58
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 135538214
- Full Text :
- https://doi.org/10.1002/anie.201814488