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Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates.
- Source :
-
Russian Journal of General Chemistry . Dec2018, Vol. 88 Issue 12, p2559-2563. 5p. - Publication Year :
- 2018
-
Abstract
- Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 88
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 135579912
- Full Text :
- https://doi.org/10.1134/S1070363218120162