The interconversion between THF·B3H7 and B3H8−: an efficient synthetic method for MB3H8 (M = Li and Na).

Authors :: Liu, Xin-Ran
Chen, Xi-Meng
Zhang, Jie
Jensen, Torben R.
Chen, Xuenian
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 4/28/2019, Vol. 48 Issue 16, p5140-5143. 4p.
Publication Year :: 2019
Abstract: An efficient synthetic method for MB3H8 (M = Li and Na) has been developed with improved yields on the basis of the investigation of the interconversion between THF·B3H7 and corresponding MB3H8. The mechanism was tentatively proposed based on the understanding of the nucleophilicity of the B–H bonding pair electrons. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 48
Issue :: 16
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 135918637
Full Text :: https://doi.org/10.1039/c9dt00843h

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