Ion concentrations in ice wedges: An innovative approach to reconstruct past climate variability.

For atmospheric gases and aerosols, snow and ice provide a useful archive of paleoenvironmental history. In the northern hemisphere, this archive has been largely limited to Greenland ice, but promising pioneering work has been done recently using chronology of an ice wedge in Barrow, northern Alaska. Here, we investigate past aerosols at the same ice-wedge sampling site, reconstructing the sea-ice fluctuations in the adjacent Beaufort Sea during the Bølling/Allerød (BA) and Younger Dryas (YD) periods. We confirm the integrity of methanesulfonate ion (MS−) concentrations in the BIWS as marine proxies, and then find that the ice wedge has a high MS− concentration through the beginning (coldest) YD periods. The high MS− concentration indicates that even during the coldest YD periods (12,900–12,700 yrBP), the near-shore region in the Alaskan Beaufort Sea near Barrow may not have been completely filled by permanent sea ice. • This is the first investigation of Pleistocene marine environment using an ice wedge. • Bromine and methanesulfonate ions are proxies of sea-ice fluctuations. • Permanent sea ice might not cover the near-shore Beaufort Sea during Younger Dryas. [ABSTRACT FROM AUTHOR]