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Engineering hierarchical CoSe/NiFe layered-double-hydroxide nanoarrays as high efficient bifunctional electrocatalyst for overall water splitting.
- Source :
-
Journal of Power Sources . Jun2019, Vol. 425, p138-146. 9p. - Publication Year :
- 2019
-
Abstract
- Exploitation of earth-abundant, cost-effective and high-efficient bifunctional electrocatalysts for overall water spitting in basic media is highly desirable, yet it remains a big challenge. Here, NiFe Layered-double-hydroxide nanosheet-anchored CoSe nanotubes (composed of plicated nanosheets) supported on Ni foam are prepared through our developed hydrothermal-selenization-hydrothermal method. Benefiting from the unique nanoarchitecture, optimized adsorption/desorption of oxygenated species at the interface (owing to the re-delocalization of electron spin status via π-donation), the bifunctional hybrid catalysts exhibit low overpotentials of 201 and 98 mV at 10 mA cm−2 for oxygen evolution reaction and hydrogen evolution reaction in 1 M KOH aqueous solution, respectively. Particularly, the full-cell only requires 1.53 V to drive a current density of 10 mA cm−2 when choosing the hybrid catalysts serving as both anode and cathode, being superior than that of the state-of-the-art commercial noble-metal based cells for overall water splitting. This work presents a general strategy to boost the oxygen evolution reaction and hydrogen evolution reaction kinetics of selenides, which is also expected to extend to other noble-metal-free catalysts. Image 1 • A three-step strategy was developed for synthesis of CoSe@NiFe-LDH electrocatalyst. • Re-localization of electron spin status was occurred at the interface. • The constructed full-cell requires 1.53 V to drive a current density of 10 mA cm−2. • CoSe@NiFe-LDH electrocatalysts exhibit both splendid OER and HER activities. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 425
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 136153901
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2019.04.014