Back to Search
Start Over
Integrated nanocomposite of LiMn2O4/graphene/carbon nanotubes with pseudocapacitive properties as superior cathode for aqueous hybrid capacitors.
- Source :
-
Journal of Electroanalytical Chemistry . Jun2019, Vol. 842, p74-81. 8p. - Publication Year :
- 2019
-
Abstract
- Aqueous rechargeable Li-ion hybrid supercapacitors are attracting increasing attention owing to their intrinsic advantages compared with nonaqueous counterpart and the combination of high energy and power densities in an individual device. However, the lack of satisfactory battery-type cathode materials with fast lithium ion storage limits the overall performance. Herein, we report a composite structure by incorporating LiMn 2 O 4 nanoparticles in graphene/carbon nanotubes network (LiMn 2 O 4 @CNTs@graphene) as superior cathode for aqueous hybrid capacitors. LiMn 2 O 4 @CNTs@graphene nanocomposite shows high capacitance with ultrafast lithium diffusion, which is mainly boosted by pseudocapacitive behavior, making it a potential candidate for hybrid supercapacitors. Hybrid devices assembled with LiMn 2 O 4 @CNTs@graphene cathode and N/S co-doped activated carbon anode exhibit an optimized overall performance with a high energy density of 62.77 Wh kg−1 and high power density of 2967.96 W kg−1 as well as good cycling performance with the capacitance retention of 90.8% after 5000 cycles. • LiMn 2 O 4 and graphene/carbon nanotubes composite was prepared to design hybrid device. • LiMn 2 O 4 particles are incorporated into graphene/ carbon nanotubes network. • The composite exhibits ultra-high rate capability. • Hybrid devices were assembled with the composite and N/S co-doped activated carbon. • The hybrid devices show excellent performance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 842
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 136443871
- Full Text :
- https://doi.org/10.1016/j.jelechem.2019.04.056