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Fe-alginate biomass-derived FeS/3D interconnected carbon nanofiber aerogels as anodes for high performance sodium-ion batteries.
- Source :
-
Journal of Alloys & Compounds . Jul2019, Vol. 795, p54-59. 6p. - Publication Year :
- 2019
-
Abstract
- The development of anode materials with a high capacity, excellent rate capability, and acceptable stability for sodium-ion batteries (SIBs) is still an urgent issue. Here, we fabricated FeS nanoparticle (NP)/three-dimensional (3D) carbon nanofiber aerogels (CNA) composites utilizing Fe-alginate aerogels as the renewable precursor. In the FeS/CNA sample, well-distributed FeS NPs were embedded on a 3D-CNA network with high electron conductivity and a large specific surface area. Impressively, the FeS/CNA sample was evaluated as an anode electrode material for SIBs, and exhibited an excellent specific capacity (473 mA h g−1 at 0.1 A g−1) and outstanding rate capacity (291 mA h g−1 at 5 A g−1). In addition, 97.4% of the capacity, 385 mA h g−1, was retained over 400 cycles at 2 A g−1, indicating the prominent cycling stability of the FeS/CNA sample. The results were ascribed to the unique structure of the FeS particles embedded on interconnected CNAs, which could boost sodium ion diffusion and facilitate electrolyte access. • Fe-alginate aerogels assure uniform dispersion of FeS NPs on porous carbon matrix. • 1D carbon fibers as transport channels can constitute porous 3D porous network. • FeS NPs and 3D network CNAs have a synergistic effect on sodium storage. • The FeS/CNA electrode reveals an excellent and stable electrochemical performance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 795
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 136645622
- Full Text :
- https://doi.org/10.1016/j.jallcom.2019.04.213