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Synthesis of highly fluorescent nitrogen-rich carbon quantum dots and their application for the turn-off detection of cobalt (II).
- Source :
-
Optical Materials . Jun2019, Vol. 92, p311-318. 8p. - Publication Year :
- 2019
-
Abstract
- In this study, we have reported easy and economical synthesis of highly fluorescent nitrogen-rich carbon quantum dots (N-CQDs). The as-prepared N-CQDs displayed strong blue color emission along with CIE co-ordinate index (0.15, 0.14). The N-CQDs possess comparatively high QY of 57% using quinine sulfate as a standard. Furthermore, the as-prepared N-CQDs defend against the high salt strength and longtime photostability over the six months of incubation. Apart from this, the as-prepared N-CQDs responded as a sensor for the 'turn-off' detection of Co2+ along with the detection limit of 0.12 μM over a linear range from 0.5 to 3 μM. The mechanistic study proved the detection of Co2+ was based on the IFE, static quenching, aggregation, and complex formation between the amino group of N-CQDs and Co2+. Moreover, the fluorescence of the quenched N-CQDs can reappear and get 'turn-on' by using GSH, AA, EDTA, and cyst; thus, the prepared N-CQDs could further execute as a probe for the Co2+ detection. Inspired by these outstanding properties, the as-prepared N-CQDs were also successfully employed for the practical application toward monitoring the trace level of Co2+ in a vitamin B-12 sample. • Nitrogen-rich carbon quantum dots (N-CQDs) were synthesized by simple hydrothermal treatment of glycine and PEI. • The synthesized N-CQDs have relatively high QY of 57% using quinine sulfate as a reference. • The N-CQDs were found to be a promising nano-probe to detect Co2+. • The feasibility of the proposed system was checked in a vitamin B-12 sample toward the Co2+ detection. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09253467
- Volume :
- 92
- Database :
- Academic Search Index
- Journal :
- Optical Materials
- Publication Type :
- Academic Journal
- Accession number :
- 136661841
- Full Text :
- https://doi.org/10.1016/j.optmat.2019.04.045