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Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis.
- Source :
-
Synlett . 2019, Vol. 30 Issue 10, p1199-1203. 5p. - Publication Year :
- 2019
-
Abstract
- We report the development of an electrocatalytic protocol for the chlorophosphinoylation of simple alkenes. Driven by electricity and mediated by a Mn catalyst, the heterodifunctionalization reaction takes place with high efficiency and regioselectivity. Cyclic voltammetry data are consistent with a mechanistic scenario based on anodically coupled electrolysis in which the generation of two distinct radical intermediates occur simultaneously on the anode and are both mediated by the Mn catalyst. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*CYCLIC voltammetry
*ELECTROLYSIS
*PHOSPHINE oxides
Subjects
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 30
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 136718186
- Full Text :
- https://doi.org/10.1055/s-0039-1689934