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π‐Ruthenium Complexes of Hexaphyrins(1.1.1.1.1.1): A Triple‐Decker Complex Bearing Two Ruthenoarene Units.
- Source :
-
Angewandte Chemie . 6/11/2019, Vol. 131 Issue 24, p8281-8284. 4p. - Publication Year :
- 2019
-
Abstract
- Ruthenium(II) π‐coordination onto [28]hexaphyrins(1.1.1.1.1.1) has been accomplished. Reactions of bis‐AuIII and mono‐AuIII complexes of hexakis(pentafluorophenyl) [28]hexaphyrin with [RuCl2(p‐cymene)]2 in the presence of NaOAc gave the corresponding π‐ruthenium complexes, in which the [(p‐cymene)Ru]II fragment sat on the deprotonated side pyrrole. A similar reaction of the bis‐PdII [26]hexaphyrin complex afforded a triple‐decker complex, in which the two [(p‐cymene)Ru]II fragments sat on both sides of the center of the [26]hexaphyrin framework. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 131
- Issue :
- 24
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 136786409
- Full Text :
- https://doi.org/10.1002/ange.201903212