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A facile method for hydroxytrifluoromethylation of alkenes with Langlois reagent and DMSO.
- Source :
-
Green Chemistry . 6/7/2019, Vol. 21 Issue 11, p2983-2987. 5p. - Publication Year :
- 2019
-
Abstract
- A practical hydroxytrifluoromethylation of alkenes using the Langlois reagent as the trifluoromethyl source and DMSO as the oxidant is described. This reaction is mild and operationally simple, without exclusion of either moisture or oxygen, allowing access to a wide range of β-trifluoromethyl alcohols in useful yields. This transformation is environmentally friendly and can be easily scaled up to gram level. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*OXIDIZING agents
*MOISTURE
*OXYGEN
*ALCOHOL
Subjects
Details
- Language :
- English
- ISSN :
- 14639262
- Volume :
- 21
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Green Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 136816674
- Full Text :
- https://doi.org/10.1039/c9gc00886a