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New Spin‐Crossover Complexes of Substituted 2,6‐Bis(pyrazol‐3‐yl)pyridines.
- Source :
-
European Journal of Inorganic Chemistry . 6/23/2019, Vol. 2019 Issue 23, p2819-2829. 11p. - Publication Year :
- 2019
-
Abstract
- Here we report two new ligands from a 2,6‐bis(pyrazol‐3‐yl)pyridine family often used in spin‐crossover research and their iron(II) and cobalt(II) complexes with the metal ion trapped in the high‐spin state in solids (according to magnetometry and X‐ray diffraction data). The iron(II) complexes, however, show a gradual spin‐crossover in acetonitrile solution, as probed by the popular Evans method and an analysis of temperature dependent chemical shifts, both rooted in variable‐temperature NMR spectroscopy. The observed stabilization of the high‐spin state by the electron‐withdrawing substituents mirrors the trend previously reported for spin‐crossover iron(II) complexes of isomeric 2,6‐bis(pyrazol‐1‐yl)pyridines. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14341948
- Volume :
- 2019
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- European Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 137109528
- Full Text :
- https://doi.org/10.1002/ejic.201900432