Experiment and model for surface tensions of 2‑diethylaminoethanol‑N‑(2‑aminoethyl)ethanolamine, 2‑diethylaminoethanol‑N‑methyl‑1,3‑propane‑diamine and 2‑diethylaminoethanol‑1,4‑butanediamine aqueous solutions

The surface tensions of 2‑diethylaminoethanol (DEAE)‑ N ‑(2‑aminoethyl)ethanolamine (AEEA), DEAE‑ N ‑methyl‑1,3‑propane‑diamine (MAPA) and DEAE‑1,4‑butanediamine (BDA) aqueous solutions have been measured by using the BZY-1 surface tension meter. The mass fractions of DEAE and AEEA/MAPA/BDA respectively ranged from 0.300 to 0.500 and 0.050 to 0.150. The temperature ranged from 303.2 K to 323.2 K. A thermodynamic equation was proposed to model the surface tension and the calculated results agreed well with the experiments. The effects of temperature and mass fraction of amines on the surface tension were demonstrated on the basis of experiments and calculations. The surface thermodynamics including surface enthalpy and surface entropy of blended amine aqueous solutions were also determined, and their temperature and mass fraction dependences were analyzed. • Surface tensions of DEAE and AEEA/MAPA/BDA aqueous solutions were measured. • Experiments were modeled satisfactorily by using a thermodynamic equation. • Surface thermodynamics including surface enthalpies and entropies were determined. • Effects of temperature and mass fraction on surface properties were illustrated. [ABSTRACT FROM AUTHOR]