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A boron nitride-polyvinylidene fluoride-co-hexafluoropropylene composite gel polymer electrolyte for lithium metal batteries.
- Source :
-
Journal of Alloys & Compounds . Sep2019, Vol. 803, p1075-1081. 7p. - Publication Year :
- 2019
-
Abstract
- A modified gel polymer electrolyte (GPE) with boron nitride (BN) additive was designed to boost the electrochemical performance of rechargeable lithium metal battery, which consists of Li-rich layered cathode and possesses a high energy density. BN, electron insulator and ion conductor, has excellent thermodynamic and electrochemical stability. BN particles were well dispersed in polyvinylidene fluoride-co-hexafluoropropylene (PVDF-HFP) polymer matrices and thus substantially enhanced the electrochemical and physical properties of the GPEs. With only 0.5 wt% BN additive, it remarkably improved the mechanical modulus and ionic conductivity (to 4.1 × 10−4 S∙cm−2) of GPEs, which was beneficial for suppressing lithium dendrite formation and fast ion transportation, respectively, thereby enabling high-performance lithium metal batteries with ultra-long cycle life and high safety at ambient temperature (25 °C) and high temperature (55 °C). A modified GPE with a multifunctional BN additive can revitalize LMBs to readily obtain a comparative ionic conductivity and remarkably improve mechanical modulus, which is beneficial for suppressing Li dendrite formation. Image 1 • We have successfully incorporated 2D BN fillers into a gel polymer electrolyte based on PVDF-HFP. • Only 0.5 wt% addition of BN can readily obtain a comparative ionic conductivity and improved mechanical modulus. • The Li 1.18 Ni 0.15 Co 0.15 Mn 0.52 O 2 /0.5 wt% BN-(PVDF-HFP)/Li cell performs a superior stability and rate capability. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 803
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 137594826
- Full Text :
- https://doi.org/10.1016/j.jallcom.2019.06.321