Fabrication of nitrogen-doped porous carbons derived from ammoniated copolymer precursor: Record-high adsorption capacity for indole.

• A series of N-doped porous carbons are synthesized via the carbonization of a N-rich copolymer. • The proper pore structures and well-distributed N species cooperate for indole adsorption. • A record high adsorptive capacity of 7.35 mmol·g−1 for indole is gotten. • The advantages of N-doped species are shown by the first-principle simulation. Reducing the nitrogen-containing compounds (NCCs) in fuel oils to ultralow level is essential for preventing the oil refining catalysts from being poisoned and for protecting the environment. Adsorptive denitrogenation is proved to be an effective mean to reduce the NCCs content. Herein, a series of N-doped porous carbons (NDPCs) in possession of proper pore structures, large surface area and moderate N species, which is verified through a series of characterization, are synthesized on the basis of the precursor copolymerized between 2,4,6 - tris (chloromethyl)mesitylene and ethylenediamine. The NDPC-700 produced from the copolymer carbonization at 700 °C exhibits a record high adsorptive capacity of 7.35 mmol·g−1 for indole in the model oils, and the stable performance on the NCC adsorption is observed after 10 cycles of regeneration and reusage. The excellent adsorption capacity is attributed to the synergistic effect between porosities and N-containing sites. Moreover, the first-principle simulation proves that the N species, in particular the N-5 species, is helpful to the improvement of the adsorption capacity for indole. [ABSTRACT FROM AUTHOR]