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Synthesis of Magnetically Separable Nanocatalyst CoFe2O4@SiO2@MIL‐53(Fe) for Highly Efficient and Selective Oxidation of Alcohols and Benzylic Compounds with Hydrogen Peroxide.
- Source :
-
ChemistrySelect . 8/7/2019, Vol. 4 Issue 29, p8477-8481. 5p. - Publication Year :
- 2019
-
Abstract
- A new methodology for the highly efficient and atom‐economic oxidation of alcohols and benzylic compounds to the corresponding aldehydes and ketones with environmental‐friendly hydrogen peroxide using a magnetic MOF nanocatalyst has been developed. We demonstrated that the resulting magnetic nanocomposite CoFe2O4@SiO2@MIL‐53(Fe) can show excellent catalytic performances in the highly selective oxidation at room temperature, based on a synergetic effect between iron sites and CoFe2O4@SiO2. The nanocatalyst offers simple operation for recovery and the recycling test showed that it could be reused for successive runs without significant degradation in catalytic activity. [ABSTRACT FROM AUTHOR]
- Subjects :
- *HYDROGEN peroxide
*ALCOHOL oxidation
Subjects
Details
- Language :
- English
- ISSN :
- 23656549
- Volume :
- 4
- Issue :
- 29
- Database :
- Academic Search Index
- Journal :
- ChemistrySelect
- Publication Type :
- Academic Journal
- Accession number :
- 137943897
- Full Text :
- https://doi.org/10.1002/slct.201901690