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Simple H2-free hydrogenation of unsaturated monoterpenoids catalyzed by Raney nickel.

Authors :
Philippov, Alexey A.
Chibiryaev, Andrey M.
Martyanov, Oleg N.
Source :
Mendeleev Communications. Jul2019, Vol. 29 Issue 4, p380-381. 2p.
Publication Year :
2019

Abstract

A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PriOH/Raney nickel system at 82 or 150 °C. Among monoterpenoids, citral and carvone underwent full conversion at 82 °C within 5 h. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09599436
Volume :
29
Issue :
4
Database :
Academic Search Index
Journal :
Mendeleev Communications
Publication Type :
Academic Journal
Accession number :
138102507
Full Text :
https://doi.org/10.1016/j.mencom.2019.07.006